Material Safety Data Sheet - Green Ammonia

Product Information

Product Name	Ammonia
Chemical Formula	NH3
Other Means of Identification	Green Ammonia; Anhydrous Ammonia; Green AAG
Product Type	Gas
Product Use	Green Fuel; Green Fertilizer; Precursor of Various Chemicals
Synonym	Green Ammonia; Green AAG
Supplier's Details	BAREGREEN INDIA LIMITED
Emergency Telephone	Police (100), Fire (101), Ambulance (102)

Hazard Identification

OSHA/HCS Status	Hazardous (OSHA Hazard Communication Standard (29CFR1910.1200))
Classification of Substance	Flammable Gases: Category 2 Gases Under Pressure: Liquefied Gas Acute Toxicity (Inhalation): Category 4 Skin Corrosion: Category 1 Serious Eye Damage: Category 1 Aquatic Hazard (Acute): Category 1
GHS Label Elements
Signal Word	Danger
Hazard Statements	Flammable Gas May form explosive mixtures with air Contains gas under pressure; may explode if heated May displace Oxygen and Cause Rapid Suffocation Harmful if Inhaled Causes Severe Skin Burns & Eye Damage Very Toxic to Aquatic Life

Precautionary Statements

General	Read and follow all Safety Data Sheets (SDS’S) before use. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Always keep container in upright position. Approach suspected leak area with caution.
Prevention	Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Avoid breathing gas. Wash hands thoroughly after handling.
Response	Collect spillage. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so.
Storage	Store locked up, Protect from sunlight, Store in a well-ventilated place.
Disposal	Dispose of contents and container in accordance with all local, regional, national and international regulations.
Otherwise Unclassified Hazards	In addition to any other important health or physical hazards, this product may displace oxygen and cause rapid suffocation.

Composition/Information on Ingredients

Substance/Mixture	Substance
Chemical Name	Ammonia
Other Means of Identification	Green Ammonia; Green AAG
Product Code	001003
Ingredient Name	Ammonia
%	100
CAS Number	7664-41-7

Note: Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

First Aid Measures

Eye Contact	Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. Call medical doctor or poison control center immediately. Chemical burns must be treated promptly by a physician.
Inhalation	Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Call medical doctor or poison control center immediately. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Skin Contact	Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Continue to rinse for at least 10 minutes. Get medical attention immediately. Call medical doctor or poison control center immediately. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion	As this product is a gas, refer to the inhalation section.

Most Important Symptoms/Effects

Eye Contact	Causes serious eye damage. Adverse symptoms may include: pain, watering, redness.
Inhalation	Harmful if inhaled. No specific data.
Skin Contact	Causes severe burns. Adverse symptoms may include: pain or irritation, redness, blistering may occur.
Frostbite	Try to warm up the frozen tissues and seek medical attention.
Ingestion	As this product is a gas, refer to the inhalation section. Adverse symptoms may include: stomach pains.

Indication of Immediate Medical Attention and Special Treatment Needed

Notes to Physician	In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Specific Treatments	No specific treatment.
Protection of First-Aiders	No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Fire-Fighting Measures

Suitable Extinguisher	Use an extinguishing agent suitable for the surrounding fire.
Unsuitable Extinguisher	None known.
Specific Hazards	Contains gas under pressure, Flammable gas, In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. This material is very toxic to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous Thermal Decomposition Products	Decomposition products may include: nitrogen oxides.
Special Protective Actions for Fire-Fighters	Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is impossible, withdraw from area and allow fire to burn. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so.
Special Protective Equipment for Fire-Fighters	Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental Release Measures

Non-emergency Personnel	Accidental releases pose a serious fire or explosion hazard. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For Emergency Responders	If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental Precautions	Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods & Materials for Containment and Cleaning Up	Small Spill: Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Large Spill: Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Handling and Storage

Precautions for Safe Handling	Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Do not breathe gas. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Store and use away from heat, sparks, open flame or any other ignition source. Empty containers retain product residue and can be hazardous. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement.
Advice on General Occupational Hygiene	Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for Safe Storage	Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Store locked up. Eliminate all ignition sources. Keep container tightly closed and sealed until ready for use. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Refer to ANSI/CGA G-2.1, Section 5.13 for electrical classification of anhydrous ammonia storage and handling areas. Where anhydrous ammonia is stored indoors, use electrical (ventilating, lighting and material handling) equipment with the appropriate electrical classification rating and use only non-sparking tools.

Exposure Controls/Personal Protection

Occupational Exposure Limits	Ammonia: - California PEL: 25 PPM (8 Hours), STEL: 35 PPM (15 Minutes) - ACGIH TLV: TWA: 25 ppm (8 hours), 17 mg/m³ (8 hours), STEL: 35 ppm (15 minutes), 24 mg/m³ (15 minutes) - OSHA PEL 1989: STEL: 35 ppm (15 minutes), 27 mg/m³ (15 minutes) - NIOSH REL: TWA: 25 ppm (10 hours), 18 mg/m³ (10 hours), STEL: 35 ppm (15 minutes), 27 mg/m³ (15 minutes) - OSHA PEL: TWA: 50 ppm (8 hours), 35 mg/m³ (8 hours)
Appropriate Engineering Controls	Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Environmental Exposure Controls	Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Hygiene Measures	Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Eye/Face Protection	Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Hand Protection	Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties.
Body Protection	Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing.
Other Skin Protection	Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Respiratory Protection	Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Physical and Chemical Properties

Physical State	Gas [Compressed gas]
Colour	Colourless
Odour	Pungent
Odour Threshold	5 ppm
pH	Approx 11.6
Melting Point	-77 °C
Boiling Point	-33 °C
Critical Temperature	132.85 °C
Flash Point	651 °C
Evaporation Rate	Not Available
Flammability	Extremely flammable in the presence of oxidizing materials.
Lower & Upper Limit	Lower: 16%; Upper: 25%
Vapour Pressure	114.1 (psig)
Vapour Density	0.59 (Air=1)
Specific Volume	0.02435 m³/mol
Gas Density	0.769 kg/m³
Relative Density	0.59 (Air=1) @ 70°F (21.1°C)
Solubility	Soluble in Water, Alcohol, and Ether
Solubility in Water	540 gm/L
Partition Coefficient	0.13
Auto Ignition Temperature	651 °C (1203.8 °F)
Decomposition Temperature	500 °C to 900 °C
Viscosity	Not Available
Flow Time (ISO-2431)	Not Available
Molecular Weight	17.03 g/mole
Aerosol Product	Ammonium Nitrate (NH4NO3), Ammonium Sulphate (NH4)2SO4
Heat of Combustion	-18589392 J/kg

Stability and Reactivity

Reactivity	No specific test data related to reactivity available for this product or its ingredients.
Chemical Stability	The product is Stable.
Possibility of Hazardous Reactions	Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to Avoid	Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.
Incompatible Materials	Oxidizers and Yellow Metals (brass & copper).
Hazardous Decomposition Products	Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Hazardous Polymerization	Under normal conditions of storage and use, hazardous polymerization will not occur.

Toxicological Information

Acute Toxicity (Oral)	Ammonia ingestion can severely impact oral swallowing due to its corrosive nature, causing burns and inflammation in the mouth and throat.
LC50 Inhalation	Rat - male - 4 h - 4.93 mg/l – vapor (ECHA)
Dermal	Ammonia can cause significant damage to the dermis, leading to burns, blisters, and tissue necrosis.
Skin Corrosion/Irritation	Rabbit, Corrosive - 4 h (OECD Test Guideline 404)
Serious Eye Damage/Eye Irritation	Causes serious eye damage.
Respiratory or Skin Sensitization	No data available.
Germ Cell Mutagenicity	Ames Test: - Test Type: Ames test - Test System: Escherichia coli/Salmonella typhimurium - Metabolic Activation: With and without metabolic activation - Method: OECD Test Guideline 471 - Result: Negative Micronucleus Test: - Test Type: Micronucleus test - Species: Mouse - Cell Type: Bone marrow - Application Route: Intra-peritoneal - Method: OECD Test Guideline 474 - Result: Negative - Remarks: (in analogy to similar products) The value is given in analogy to ammonium chloride
Carcinogenicity	No data available.
Reproductive Toxicity	No data available.
Specific Target Organ Toxicity (Single Exposure)	No data available.
Specific Target Organ Toxicity (Repeated Exposure)	No data available.
Aspiration Hazard	No data available.

Ecological Information

Toxicity	Toxicity to Fish: - Flow-through test LC50 - Pimephales promelas (fathead minnow) - 0.068 mg/l - 96 h - Remarks: (in analogy to similar products) (ECHA) The value is given in analogy to the following substances: ammonium sulphate Toxicity to Daphnia and Other Aquatic Invertebrates: - Static test LC50 - Daphnia magna (Water flea) - 101 mg/l - 48 h (ECHA) - EC50 - Daphnia pulicaria - 1.16 mg/l - 48 h (Lit.) Toxicity to Fish (Chronic Toxicity): - Flow-through test NOEC - Ictalurus punctatus - 0.048 mg/l - 31 d (OECD Test Guideline 215) Toxicity to Daphnia and Other Aquatic Invertebrates (Chronic Toxicity): - Flow-through test LC50 - Daphnia magna (Water flea) - 4.07 mg/l - 96 h (US-EPA) - Remarks: (in analogy to similar products) The value is given in analogy to the following substances: ammonium chloride - Flow-through test NOEC - Daphnia magna (Water flea) - 0.79 mg/l - 96 h (US-EPA) - Remarks: (in analogy to similar products) The value is given in analogy to the following substances: ammonium chloride
Persistence and Degradability	Biodegradability Result: rapidly biodegradable Remarks: Readily biodegradable.
Bioaccumulative Potential	No data available
Mobility in Soil	No data available
Results of PBT and vPvB Assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine Disrupting Properties	Assessment: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other Adverse Effects	No data available

Waste Treatment Methods

Product	Pressurised gas bottle: dispose of only in empty condition!